{μ-6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylyl­idene)]diphenolato-1κ4 O 6,O 1,O 1′,O 6′;2κ4 O 1,N,N′,O 1′}(methanol-1κO)(tetra­fluoridoborato-1κ2 F,F′)-2-copper(II)-1-sodium

نویسندگان

  • Ting Gao
  • Yu Yang
  • Po Gao
  • Ju-Wen Zhang
  • Jing-Lin Yang
چکیده

In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetra-fluorido-borate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio.

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{μ-6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-1κ4 O 6,O 1,O 1′,O 6′:2κ4 O 1,N,N′,O 1′}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I)

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{μ-6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diyl­bis(nitrilo­methyl­idyne)]diphenolato-1κ4 O 6,O 1,O 1′,O 6′:2κ4 O 1,N,N′,O 1′}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium

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{6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-1κ4 O 1,O 1′,O 6,O 6′:2κ4 O 1,N,N′,O 1′}(ethanol-1κO)-μ-nitrato-1:2κ2 O:O′-dinitrato-1κ4 O,O′-samarium(III)zinc(II)

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011